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Due to the significant knowledge on the ring-opening polymerization of six-membered cyclic carbonates and the known higher reactivity of two primary hydroxyl groups compared to the secondary hydroxyl group during polycondensation, linear poly(1,3-glycerol carbonate)s and polyesters synthesized from the polycondensation of glycerol with diacid, e.g., adipic acid, are the two main structural classes of 1,3-linked glycerol polymers synthesized, respectively